Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide

• Autoři: MAREK Jaromír; KOPEL P.; TRÁVNÍČEK Z.
• Rok publikování: 2003
• Druh: Článek v odborném periodiku
• Časopis / Zdroj: Acta Crystallographica Section C: Crystal Structure
• Fakulta / Pracoviště MU: Přírodovědecká fakulta
• Obor: Anorganická chemie
• Klíčová slova: Hydrogen bonding; Trithiocyanuric acid
• Popis: The title compound, [Na(C12H8N2)3](C3H2N3S3), contains an Na+ centre which is ionicly bonded to three 1,10-phenanthroline (phen) ligands and one trithiocyanurate(1-) (ttcH2) anion. In the crystal structure, the anions are linked via hydrogen bonds to form linear chains. The S and H atoms of the ttcH2 anion participate in intermolecular N-HS hydrogen bonding, with NS distances of 3.298 (2) and 3.336 (2) A. The phen ligands are almost parallel, with dihedral angles of 3.92 (5), 11.75 (5) and 15.45 (5) deg; moreover, they are nearly perpendicular to the ttcH2 chains, with angles of 81.94 (7), 85.86 (7) and 85.96 (7)deg.

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