New mixed-ligand organoaluminum heteroarylalkenolates

Varování

Publikace nespadá pod Fakultu sportovních studií, ale pod Přírodovědeckou fakultu. Oficiální stránka publikace je na webu muni.cz.
Autoři

PODHORSKÝ Ján BABIAK Michal PINKAS Jiří HEGEMANN Corinna MATHUR Sanjay MORAVEC Zdeněk

Rok publikování 2021
Druh Článek v odborném periodiku
Časopis / Zdroj Polyhedron
Fakulta / Pracoviště MU

Přírodovědecká fakulta

Citace
www https://doi.org/10.1016/j.poly.2020.114953
Doi http://dx.doi.org/10.1016/j.poly.2020.114953
Klíčová slova aluminum; heteroarylalkenolate; alanes; metal organic; crystallography
Popis We have successfully synthesized and structurally characterized eight novel aluminum compounds with N,O-beta-heteroarylalkenolate ligands (L) containing a CF3 group. The reactions of 3,3,3-trifluoro(dimethyl-1,3-oxazol-2-yl)propen-2-ol (H-DMOTFP), 3,3,3-trifluoro(pyridin-2-yl)propen-2-ol (H-PyTFP), and 3,3,3-trifluoro(1,3-benzthiazol-2-yl)propen-2-ol (H-BTTFP) with chloroalanes R2AlCl and RAlCl2 (R = Et, iBu) in dry aprotic solvents provided complexes displaying several types of molecular structures. Effects of ligand, solvent, and crystallization conditions were investigated. The most common and stable products were chloride complexes [AlCl(L)2] with five-coordinated aluminum centers represented by [AlCl(DMOTFP)2] (1) and [AlCl(PyTFP)2] (2). A six-coordinated aluminum complex with a coordinated THF was obtained as [AlCl(THF)(PyTFP)2] (2.THF). Complexes with preserved alkyl groups [AlR(L)2] were isolated as [AlEt(BTTFP)2] (3) and [AliBu(DMOTFP)2] (4). An intermolecular rearrangement led to an ionic complex [Al(PyTFP)2(THF)2][iBuAlCl3] (5). In the reactions of H-BTTFP, the complex 3 with two ligands, as well as molecules [AlRCl(L)] with only one ligand attached were characterized as [AlEtCl(BTTFP)] (6) and [AliBuCl(BTTFP)] (7). The thermal properties of obtained complexes were investigated by TG/DSC and HT/XRD analyses.
Související projekty:

Používáte starou verzi internetového prohlížeče. Doporučujeme aktualizovat Váš prohlížeč na nejnovější verzi.

Další info