Role of Glycoluril Oligomers in Chemistry

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Publikace nespadá pod Fakultu sportovních studií, ale pod Fakultu sociálních studií. Oficiální stránka publikace je na webu muni.cz.
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GILBERG Laura ŠINDELÁŘ Vladimír

Rok publikování 2013
Druh Konferenční abstrakty
Fakulta / Pracoviště MU

Fakulta sociálních studií

Citace
Popis Recently acyclic oligomeric structures based on glycoluril attracted attention because of their easy modification, ability to act as host molecules, and their use for the synthesis of CB. They are usually synthesized by the controlled condensation of glycoluril units without or with substitution. The attachment of protective sidewalls yields clip-like host structures that show different recognition properties and solubilities compared to macrocyclic structures. An example for the synthesis of such a host molecule is shown Tetramer with xylylene sidewalls. X-ray diffraction showed that it forms dimeric aggregates. However, no dimerisation was observed in solution. The tetramer binds to organic cations and binding constants were determined. The binding constant were compared to a watersoluable tetramer and CB6.
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