Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies

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Authors

SVOBODOVÁ Ivona HAVLÍČKOVÁ Jana PLUTNAR Jan LUBAL Přemysl KOTEK Jan HERMANN Petr

Year of publication 2009
Type Article in Periodical
Magazine / Source Eur. J. Inorg. Chem.
MU Faculty or unit

Faculty of Science

Citation
Web http://dx.doi.org/10.1002/ejic.200900358
Field Inorganic chemistry
Keywords X-ray crystal structure; macrocyclic ligands; phosphonate complexes; copper(ii) complexes; cyclam derivatives; zinc(ii) complexes; cadmium(ii) complexes; complexation / decomplexation kinetics; radiopharmaceuticals
Description Bis(phosphonic) acid derivative of cyclam was synthesized by an improved synthesis. Thermodynamic stability of divalent metal complexes was determined. Formation and decomplexation kinetics of complexes with divalent copper, zinc and cadmium was investigated.
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