Luminescence properties of Eu(III) coordination polymers with bis(diphenylphosphino)alkane dioxides

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Authors

PEKÁRKOVÁ Pavla TÁBORSKÝ Petr SPÍCHAL Zdeněk NEČAS Marek

Year of publication 2008
Type Article in Proceedings
Conference XIXth Slovak-Czech Spectroscopic Conference Book of Abstracts
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords Eu(III) luminescence; coordination polymers
Description Europium(III) salts were allowed to react with bis(diphenylphosphino)alkane dioxides Ph2P(O)(CH2)nP(O)Ph2 (n = 2, 4, 6) to obtain polymeric and binuclear complexes. In this work, we present a study on spectral properties of lanthanide(III) coordination polymers with bis(diphenylphosphino)alkane ligands where alkane is ethyl, butyl or hexyl and lanthanide salt is EuCl3 or Eu(NO3)3) to find relationship between luminescence properties and structure of newly synthesized compounds.
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