The Photo-Favorskii Reaction of p-Hydroxyphenacyl Compounds Is Initiated by Water-Assisted, Adiabatic Extrusion of a Triplet Biradical

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Authors	GIVENS Richard HEGER Dominik HELLRUNG Bruno KAMDZHILOV Yavor MAC Marek CONRAD Peter COPE Elizabeth LEE Jong MATA-SEGREDA Julio SCHOWEN Richard WIRZ Jakob
Year of publication	2008
Type	Article in Periodical
Magazine / Source	J. Am. Chem. Soc.
MU Faculty or unit	Faculty of Science
Citation
Field	Nuclear and quantum chemistry, photochemistry
Keywords	photo-favorsii reaction; p-hydroxyphenacyl; adiabatic extrusion; photoremovable protecting group
Description	The sequence of intermediates occurring in the photo-Favorskii rearrangement of p-hydroxyphenacyl derivatives in aqueous solutions is established.
Related projects:	Proteins in metabolism and interaction of organisms with the environment