Fluorinated photoremovable protecting groups: the influence of fluoro substituents on the photo-Favorskii rearrangement

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Authors	STENSRUD Kenneth F. HEGER Dominik ŠEBEJ Peter WIRZ Jakob GIVENS Richard S.
Year of publication	2008
Type	Article in Periodical
Magazine / Source	Photochemical & Photobiological Sciences
MU Faculty or unit	Faculty of Science
Citation
Web	http://www.rsc.org/Publishing/Journals/PP/article.asp?doi=b719367j
Field	Nuclear and quantum chemistry, photochemistry
Keywords	Photoremovable Protecting Group; p-Hydroxyphenacyl Protecting Group; Fluorinated Photoremovable Protecting Groups; Laser Flash Photolysis
Description	To further explore the nature of the photo-Favorskii rearrangement and its commitment to substrate photorelease from p-hydroxyphenacyl (pHP), an array of ten new fluorinated pHP gama-aminobutyric acid (GABA) derivatives was synthesized and photolyzed.
Related projects:	Proteins in metabolism and interaction of organisms with the environment