13C CHEMICAL SHIFT TENSORS IN REGIOISOMERS OF N-SUBSTITUTED ADENINES

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Authors	MALIŇÁKOVÁ Kateřina STANDARA Stanislav MAREK Radek
Year of publication	2008
Type	Conference abstract
MU Faculty or unit	Faculty of Science
Citation
Description	Solid state NMR spectroscopy was utilized to study three regioisomers of N-benzylated adenine. Slow-spinning CP/MAS experiment was performed and chemical shift tensor principal values for nucleobase carbons were extracted. Orientations of the principal components in the molecular frame were determined with the use of DFT calculations. Results for the three regioisomers were compared and the differences described.
Related projects:	Proteins in metabolism and interaction of organisms with the environment Biomolecular centre