(mu(3)-Trithiocyanurato-kappa N-6(1),S-2 : N-3,S-4 : N-5,S-6) tris[(N,N,N ',N '',N ''-pentamethyldiethylenetriamine-kappa N-3,N ',N '')copper(II)] tris(perchlorate)

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Authors	TRÁVNÍČEK Z. MAREK Jaromír ČERMÁKOVÁ Š.
Year of publication	2007
Type	Article in Periodical
Magazine / Source	Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	CRYSTAL
Description	In the title compound, [Cu-3(C9H23N3)(3)(C3N3S3)](ClO4)(3), the three Cu-II centres, related by the body-diagonal threefold rotation symmetry along [ 111], are bridged by a trithiocyanurate( 3 -) anion ( ttc), with each centre having a considerably distorted trigonal - bipyramidal geometry and bonded to three N atoms of a tridentate N, N, N', N '', N ''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of the ttc ligand. The secondary structure is stabilized by a variety of weak hydrogen bonds of the type C - H center dot center dot center dot O ( H center dot center dot center dot A < 2.7 angstrom) connecting the cation and perchlorate anions.
Related projects:	Physical and chemical properties of advanced materials and structures