Thermodynamic characteristics of complex formation in alumazene-pyridine system

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Authors

TIMOSHKIN Alexey Y. CONG Trinh PINKAS Jiří

Year of publication 2006
Type Article in Proceedings
Conference 11th International Symposium on Inorganic Ring Systems
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords Alumazene; pyridine; static tensimetric method; B3LYP/6-31G*
Description The thermodynamics of complex formation between the inorganic benzene alumazene AZ=[MeAlN(2,6-iPr2C6H3)]3 and pyridine Py=C5H5N has been investigated experimentally and theoretically. Thermodynamic characteristics of the complex dissociation in the temperature range 25-200 oC have been derived from the vapor pressure - temperature dependence measurements by the static tensimetric method with glass membrane as null-manometer.
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