The synthesis and crystal structures of two-dimensional coordination polymers of Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 with praseodymium

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Authors

SPÍCHAL Zdeněk NEČAS Marek PINKAS Jiří NOVOSAD Josef

Year of publication 2004
Type Article in Periodical
Magazine / Source INORGANIC CHEMISTRY
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords lanthanide layered network coordination polymers
Description Reactions of Pr(NO3)3 with Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in bridging fashion. The praseodymium cations with spacer ligands form two-dimensional building blocks assembling into either square grid or herringbone architecture.
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