Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor

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Authors

JANCIK Vojtech PINEDA Leslie W. PINKAS Jiri ROESKY Herbert W. NECULAI Dante NECULAI Ana M. HERBST-IRMER Regine

Year of publication 2004
Type Article in Periodical
Magazine / Source Angewandte Chemie International Edition
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords aluminum amides carbenes hydroxides
Description We have presented a novel method for preparing aluminum amides and hydroxides from the corresponding chlorides. The main byproduct - N,N-di-tbutylimidazolium chloride - can be easily separated from the product by filtration and recycled to the free base. LAl(NH2)2 is to the best of our knowledge the first monomeric main-group metal diamide containing two terminal NH2 groups.
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