Monofunctionalized Fluorinated Bambusurils and Their Conjugates for Anion Transport and Extraction

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Authors

DE SIMONE Nicola Alessandro CHVOJKA Matúš LAPEŠOVÁ Jana MARTÍNEZ-CRESPO Luis SLÁVIK Petr SOKOLOV Jan BUTLER Stephen J. VALKENIER Hennie ŠINDELÁŘ Vladimír

Year of publication 2022
Type Article in Periodical
Magazine / Source Journal of Organic Chemistry
MU Faculty or unit

Faculty of Science

Citation
Web https://doi.org/10.1021/acs.joc.2c00870
Doi http://dx.doi.org/10.1021/acs.joc.2c00870
Keywords Anions; Assays; Extraction; Macrocycles; Reaction products
Description Bambusurils are macrocyclic molecules that are known for their high binding affinity and selectivity toward anions. Here, we present the preparation of two bambusurils bearing fluorinated substituents and one carboxylic function. These monofunctionalized bambusurils were conjugated with crown ether and cholesterol units. The resulting conjugates were successfully tested in liquid–liquid extraction of inorganic salts and chloride/bicarbonate transport across lipid bilayers.
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