Constitution of the binary M-Sb systems (M = Ti, Zr, Hf) and physical properties of MSb2
| Authors | |
|---|---|
| Year of publication | 2018 |
| Type | Article in Periodical |
| Magazine / Source | Intermetallics |
| MU Faculty or unit | |
| Citation | |
| Web | http://dx.doi.org/10.1016/j.intermet.2017.12.014 |
| Doi | http://dx.doi.org/10.1016/j.intermet.2017.12.014 |
| Field | Physical chemistry and theoretical chemistry |
| Keywords | Titanium antimonides;Phase equilibria;crystal structure;Physical properties;Mechanical properties;Thermoelectrics |
| Description | This study is closely related to the chemical interactions in thermoelectric joints of a hot metal electrode with p and n-type skutterudite. First and complete phase diagram has been constructed for the Ti-Sb system as well as partial phase diagrams for the systems Zr-Sb and Hf-Sb. Physical properties were evaluated for the binary compounds MSb2 (M = Ti, Zr, Hf). These data will serve to evaluate the potential of these compounds for thermoelectric devices, where these phases predominantly appear in the diffusion zones of the hot metal electrode with p- and n-type skutterudite. |
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