Constitution of the binary M-Sb systems (M = Ti, Zr, Hf) and physical properties of MSb2

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Authors

TAVASSOLI Ali GRYTSIV Andryi FAILAMANI Fainan ROGL Gerda PUCHEGGER Stephan MÜLLER Herbert BROŽ Pavel ZELENKA František MACCIO Daniele SACCONE Adriana GIESTER Gerald BAUER Ernst ZEHETBAUER Michal ROGL Peter Franz

Year of publication 2018
Type Article in Periodical
Magazine / Source Intermetallics
MU Faculty or unit

Faculty of Science

Citation
Web http://dx.doi.org/10.1016/j.intermet.2017.12.014
Doi http://dx.doi.org/10.1016/j.intermet.2017.12.014
Field Physical chemistry and theoretical chemistry
Keywords Titanium antimonides;Phase equilibria;crystal structure;Physical properties;Mechanical properties;Thermoelectrics
Description This study is closely related to the chemical interactions in thermoelectric joints of a hot metal electrode with p and n-type skutterudite. First and complete phase diagram has been constructed for the Ti-Sb system as well as partial phase diagrams for the systems Zr-Sb and Hf-Sb. Physical properties were evaluated for the binary compounds MSb2 (M = Ti, Zr, Hf). These data will serve to evaluate the potential of these compounds for thermoelectric devices, where these phases predominantly appear in the diffusion zones of the hot metal electrode with p- and n-type skutterudite.
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